Cooperative Gold Nanoparticle Stabilization by Acetylenic Phosphaalkenes

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Cooperative Gold Nanoparticle Stabilization by Acetylenic Phosphaalkenes

Acetylenic phosphaalkenes (APAs) are used as a novel type of ligands for the stabilization of gold nanoparticles (AuNP). As demonstrated by a variety of experimental and analytical methods, both structural features of the APA, that is, the P=C as well as the C≡C units are essential for NP stabilization. The presence of intact APAs on the AuNP is demonstrated by surface-enhanced Raman spectrosco...

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ژورنال

عنوان ژورنال: Angewandte Chemie International Edition

سال: 2015

ISSN: 1433-7851

DOI: 10.1002/anie.201504834